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Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings

Résumé

An access to functionalised eight-membered carbocyclic ring compounds was developed by simply stirring an unusual vinylogous Donor-Acceptor Cyclopropane (DAC) in boiling o-xylene. Both experimental and computational studies were performed to explain the diastereoselectivity/regioselectivity transfer observed and to provide an overall picture of the mechanism.

Domaines

Chimie organique

Dates et versions

hal-04153740 , version 1 (06-07-2023)

Licence

Domaine public

Identifiants

  • HAL Id : hal-04153740 , version 1

Citer

Kévin Masson, Maxime Dousset, Bohdan Biletskyi, Sara Chentouf, Jean‐valère Naubron, et al.. Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings. France. 2023. ⟨hal-04153740⟩
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