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Image Année : 2022

Dissipative Acid-Fueled Reprogrammable Supramolecular Materials

Résumé

Smart materials reversibly changing properties in response to a stimuli are promising for a broad array of applications. In this article, we report the use of trichloroacetic acid (TCA) as fuel to create new types of timecontrolled materials switching reversibly from a gel to a solution (gel−sol−gel cycle). Applying various neutral amines as organogelators, TCA addition induces amine protonation, switching the system to a solution, while TCA decarboxylation over time enables a return to the initial gel state. Consequently, the newly obtained materials possess interesting time-dependent properties applied in the generation of remoldable objects, as an erasing ink, as chiroptical switches, or for the generation of new types of electrical systems.

Dates et versions

hal-03695509 , version 1 (14-06-2022)

Licence

Domaine public

Identifiants

  • HAL Id : hal-03695509 , version 1

Citer

Enzo Olivieri, Baptiste Gasch, Guilhem Quintard, Jean-Valère Naubron, Adrien Quintard. Dissipative Acid-Fueled Reprogrammable Supramolecular Materials. Illustration. France. 2022. ⟨hal-03695509⟩
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